Pat the fresh scallops dry with paper towels. Season with a pinch of white pepper.
Bring water to a boil in a pot. Add a pinch of salt. Blanch the gai lan for 1-2 minutes until tender-crisp. Drain and set aside.
Heat cooking oil in a wok over medium-high heat. Add minced garlic and minced ginger, stir-fry until fragrant, about 30 seconds.
Add the prepared scallops to the wok. Stir-fry for 1-2 minutes until they are lightly seared and almost cooked through. Remove scallops from the wok and set aside.
Return the gai lan to the wok. Add XO sauce, Shaoxing wine, and sugar. Stir-fry for 1 minute to combine.
Return the scallops to the wok. Pour in the cornstarch slurry and stir quickly until the sauce thickens. Serve immediately.
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