Pat chicken thighs dry with paper towels to remove excess moisture.
Heat vegetable oil in a large wok or braising pot over medium-high heat. Working in batches, sear chicken thighs skin-side down until golden brown.
Flip chicken and sear the other side briefly. Transfer to a plate.
In the same pot, add minced garlic, ginger slices, dried red chilies, and scallion white parts. Stir-fry until fragrant.
Add five-spice powder and stir constantly for 30 seconds until aromatic.
Pour in dark soy sauce, light soy sauce, oyster sauce, and sugar. Stir to combine.
Return chicken thighs to the pot, skin-side up. Add chicken stock and star anise.
Bring to a boil, then reduce heat to medium-low. Cover and simmer for 30 minutes until chicken is tender.
Uncover and increase heat to medium. Simmer for 5-8 minutes more to reduce sauce until glossy and thickened.
Drizzle with sesame oil. Transfer to a serving plate, garnish with chopped scallion greens and sesame seeds.
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